SYNERGISTIC MANGANESE OXIDE AND COCONUT HUSK NANOPARTICLES HYBRID COATING FOR SUSTAINABLE PIPELINE CORROSION CONTROL IN ACIDIC ENVIRONMENT

Authors

  • P.A. Oghenekowho Federal University of Petroleum Resources Effurun
  • C. I. Ajuwa Federal University of Petroleum Resourses Effurun, Nigeria
  • B. U. Oreko Federal University of Petroleum Resourses Effurun, Nigeria

DOI:

https://doi.org/10.4314/njt.v44i3.5

Keywords:

Corrosion, Novel Hybrid coating, Epoxy resin, Nanoparticles, Petroleum pipelines, EIS, PDP

Abstract

In the oil and gas industry, corrosion is a major problem that can result in pipeline breakdowns and economic losses. This project aims to develop a novel hybrid corrosion protection coating for petroleum pipeline-grade steel using epoxy resin reinforced with manganese oxide and coconut husk nanoparticles (CHNP). Response Surface Methodology was used to develop and optimise the hybrid coating (RSM). Potentiodynamic polarisation (PDP) and Electrochemical Impedance Spectroscopy (EIS) techniques were used to assess its performance. The findings showed that the corrosion resistance of the developed hybrid coating was greatly enhanced by the addition of CHNP and MNO2, and a maximum corrosion efficiency of 93% was attained at 4.45 weight percent CHNP and 2.03 weight percent MNO₂ in 0.5 mol.dm⁻³ H2SO4. The results obtained showed that the combination of CHNP and MnO2 is suitable for formulating corrosion protection coating for carbon steels.

References

[1] Ihamdane, R. Tiskar, M. Outemsaa, B. Zelmat, L. Dagdag, O. Berisha, A. Berdimurodov, E. Ebenso, E. and Chaouch, A “Essential Oil of Origanum vulgare as a Green Corrosion Inhibitor for Carbon Steel in Acidic Medium,” Arabian Journal for Science and Engineering, 48, p. 7685–7701, 2023.

[2] Nguyen, T. Park, J. Kim, W. S. Nahm, S. H. and Beak, U. B “Effect of low partial hydrogen in a mixture with methane on the mechanical properties of X70 pipeline steel,” International Journal of Hydrogen Energy, 45(3), pp. 2368-2381, 2020.

[3] Prasad, A. R. Kunyankandy, A. and Joseph, A. “Corrosion Inhibition in Oil and Gas Industry-Economic Considerations,” in Corrosion Inhibition in Oil and Gas Industry, Saji, V. S. and Umoren, S. A. Eds., Wiley Online Library, 2020.

[4] Alamri, A. H. “Localized corrosion and mitigation approach of steel materials used in oil and gas pipelines – An overview,” Engineering Failure Analysis, 116, 2020.

[5] WCO, “World Corrosion Organisation,” 24 April 2024. [Online]. Available: https://corrosion.org/Events/Corrosion+Awareness+Day/2024_+April+24-p-2706.html. [Accessed 5 August 2025].

[6] Olugbode, M. “FG Decries Massive Effect of Corrosion on Nigeria’s Economy,” This Day, August 6 2023. [Online]. Available: https://www.thisdaylive.com/2023/10/25/fg-decries-massive-effect-of-corrosion-on-nigerias-economy/. [Accessed August 2025].

[7] Fotovvati, B. Namdari, N. and Dehghanghadikolaei, A. “On Coating Techniques for Surface Protection: A Review,” Journal of Manufacturing and Materials Processing, 3(1), 2019.

[8] Sharun, V. Rajasekaran, M. Kumar, S. S. Tripathi, V. Sharma, R. Puthilibai, G. Sudhakar, M. and Negash, K. “Study on Developments in Protection Coating Techniques for Steel,” Advances in Materials Science and Engineering, 2022, pp. 1-10, 2022.

[9] Tusher, M. Imam A. and Shuvo, M. “Future and Challenges of Coating Materials,” in Coating Materials. Materials Horizons: From Nature to Nanomaterials, Verma, A. Sethi, S. and Ogata, S. Eds., Singapore, Springer, 2023.

[10] Desai, P. D. Pawar, C. B. Avhad, M. S. and More, A. P. “Corrosion inhibitors for carbon steel: A review,” Vietnam Journal of Chemistry, 61(1), pp. 15-42, 2023.

[11] Wu, Y. Wu, Y. Sun, Y. Zhao, W. and Wang, L. “2D Nanomaterials Reinforced Organic Coatings for Marine Corrosion Protection: State of the Art, Challenges, and Future Prospectives,” Advanced Materials, 36(37), pp. 1-31, 2024.

[12] Udoh, T. H. and Sunday, M. U. “Investigation of Corrosion Inhibition Potential of Selected Biological Inhibitors,” Nigerian Journal of Technology (NIJOTECH), 41(2), pp. 263-269, 2022.

[13] Ajike, E. E. Lebe, A. N. N. E. C. Ogwo, K. D. and Ahamfula, C. Y. “Inhibitive Properties of Garcinia Kola (GK) in Alkaline Medium of Aluminium Alloy (AA4007),” Nigerian Journal of Technology (NIJOTECH), 43(2), pp. 272-278, 2024.

[14] Sun, H. Li, L. and Li, W. “Application of organosilanes in titanium-containing organic–inorganic hybrid coatings,” Journal of Materials Science, 57(29), pp. 13845–13870, 2022.

[15] Ragheb, D. M. Abdel-Gaber, A. M. Mahgoub, F. M. and Mohamed, M. E. “Eco-friendly method for construction of superhydrophobic graphene-based coating on copper substrate and its corrosion resistance performance,” Scientific Reports, 12, 2022.

[16] Yue, P. Zhang, M. Zhao, T. Liu, P. Peng, F. and Yang, L. “Eco-friendly epoxidized Eucommia ulmoides gum based composite coating with enhanced super-hydrophobicity and corrosion resistance properties,” Industrial Crops and Products, 214, 2024.

[17] Ouarga, A. Lebaz, N. Tarhini, M. Noukrati, H. Barroug, A. Elaissari A. and Youcef, H. B. “Towards smart self-healing coatings: Advances in micro/nano-encapsulation processes as carriers for anti-corrosion coatings development,” Journal of Molecular Liquids, 354, 2022.

[18] Aramayo, M. A. F. and Aoki, I. V. “Self-healing capability of epoxy coating using dual-component microcapsules under immersion,” Journal of Iron and Steel Research International, 32(5), 2025.

[19] Thomas, D. Philip, R. R, E. Sindhu, R. Ulaeto, S. B. Pugazhendhi, A. and Awasthi, M. K. “Developments in smart organic coatings for anticorrosion applications: a review,” Biomass Conversion and Biorefinery, 12, pp. 4683–4699, 2022.

[20] Kumari, S. and Saini, A. D. V. “Metal oxide based epoxy coatings for corrosion protection of steel,” Materials Today: Proceedings, vol. 43, pp. 3105-3109, 2021.

[21] Eskandari, M. Shanaghi, A. Kamani, M. and Niari, M. A. “Effect of nano-metal oxides (ZnO, Al2O3, CuO, and TiO2) on the corrosion behaviour of a nano-metal oxide/epoxy coating applied on the copper substrate in the acidic environment,” Applied Nanoscience, 11(5), pp. 1605–1615, 2021.

[22] Muresan, L. M. “Nanocomposite Coatings for Anti-Corrosion Properties of Metallic Substrates,” Materials, vol. 16, no. 14, 2023.

[23] Ashibudike, O. E. Iweriolor S. and Oreko, B. U. “Electrochemical Corrosion Inhibition of Cobalt-Graphene Nano-Composite on Mild Steel in Acidic Corrosion Environment,” Nigerian Journal of Technology (NIJOTECH), 43(2), pp. 261-271, 2024.

[24] Azani, N. F. S. M. Zahari, H. M. M. A Sophie, P. Brosse, N. and Hazwan, M. H. “Preparation and characterizations of oil palm fronds cellulose nanocrystal (OPF-CNC) as reinforcing filler in epoxy-Zn rich coating for mild steel corrosion protection,” International Journal of Biological Macromolecules, 353, pp. 385-398

[25] Oisakede, M. “Evaluation of the Thermal properties of Epoxy-Agro waste (Egg shell and Palm kernel shell) Nanoparticle coating for Mild Steel.,” Black Sea Journal of Engineering and Science, 4(4), pp. 179-182, 2021.

[26] Vaithilingam, S. ThangavelRavivarman, R. and Muthukaruppan, A “Development of cashew nut shell carbon reinforced thiourea based biophenolic benzoxazine-epoxy composites: High performance biobased coating materials,” Polymer Composites, 41(5), pp. 1950-1961, 2020.

[27] Azadi, M. Mehrabadi, M. and Hafazeh, A. “The corrosion inhibition efficiency of carbon steel in HCl solution utilizing pistachio soft hull extract: Experimental measurements, DFT and MD simulations,” Results in Engineering, 26, pp. 1-13, 2025.

[28] Ossila, “Ossila BV,” 15 February 2025. [Online]. Available: https://www.ossila.com/products/manganese-iv-oxide-powder.

Downloads

Published

2025-10-15

Issue

Section

Chemical, Industrial, Materials, Mechanical, Metallurgical, Petroleum & Production Engineering

How to Cite

SYNERGISTIC MANGANESE OXIDE AND COCONUT HUSK NANOPARTICLES HYBRID COATING FOR SUSTAINABLE PIPELINE CORROSION CONTROL IN ACIDIC ENVIRONMENT. (2025). Nigerian Journal of Technology, 44(3), 411-421. https://doi.org/10.4314/njt.v44i3.5